Deep Electroreductive Chemistry: Harnessing Carbon- and Silicon-Based Reactive Intermediates in Organic Synthesis
نویسندگان
چکیده
ADVERTISEMENT RETURN TO ISSUEPREVViewpointNEXTDeep Electroreductive Chemistry: Harnessing Carbon- and Silicon-Based Reactive Intermediates in Organic SynthesisWen ZhangWen ZhangDepartment of Chemistry Chemical Biology, Cornell University, Ithaca, New York 14853, United StatesMore by Wen Zhanghttps://orcid.org/0000-0002-0704-3463, Weiyang GuanWeiyang GuanDepartment Guan, Jesus I. Martinez AlvaradoJesus AlvaradoDepartment Alvarado, Luiz F. T. NovaesLuiz NovaesDepartment Novaeshttps://orcid.org/0000-0003-1209-2865, Song Lin*Song LinDepartment States*Email: [email protected]More Linhttps://orcid.org/0000-0002-8880-6476Cite this: ACS Catal. 2023, 13, 12, 8038–8048Publication Date (Web):May 31, 2023Publication History Received14 March 2023Published online31 May inissue 16 June 2023https://doi.org/10.1021/acscatal.3c01174Copyright © 2023 American SocietyRIGHTS & PERMISSIONSArticle Views4512Altmetric-Citations-LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum full text article downloads since November 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated to reflect usage leading up last few days.Citations number other articles citing this article, calculated Crossref daily. Find more information about citation counts.The Altmetric Attention Score is a quantitative measure attention that research has received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence for given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InReddit (3 MB) Get e-AlertscloseSUBJECTS:Alkyls,Anions,Halogens,Hydrocarbons,Inorganic compounds e-Alerts
منابع مشابه
New reactive intermediates in organic chemistry
Physical organic chemistry (POC) and reactive intermediate chemistry (RIC) belong to the core subjects of organic chemistry. During the 1990s and 2000s both had become increasingly less fashionable, and in many countries, the mass of active researchers working in POC and RIC was in danger of becoming subcritical. Consequently, in 2003, the WhitesidesReport on the status of chemistry in Great Br...
متن کاملDisubstituted Carbenium Ions as Reactive Intermediates in Organic Chemistry
Recent results in the chemistry of disubstituted carbenium ions (vinyl cations and phenyl cations) are described separately under three different sections: From kinetic and solvolytic data of several 1—cyclobutenyl nonaflates, the intermediacy of a non-classical vinyl cation, namely the 1-cyclobutenyl cation 2 is established. Cycloaddition reactions of solvolytically generated vinyl cations wit...
متن کاملsynthesis of 3-aryl-2h-benzo[b]-1,4-oxazines in [omim]bf4 and reduction of organic compounds in methylimidazolium formate
در این پروژه ترکیبات 3-آریل-2h-بنزو[b]-4،1-اکسازین ها از مواد اولیه تجاری مشتقات دو آمینو فنول و ?-هالو کتون های آروماتیک در مایع یونی 1-اکتیل-3-متیل ایمیدازولیوم تترا فلورو بورات([omim]bf4) سنتز شده است. این واکنش توسط باز پتاسیم کربنات محلول از طریق o-آلکیلاسیون و سپس یک واکنش آمیداسیون درون مولکولی خود بخود در مدت زمان کوتاه انجام می شود. ترکیبات 4،1-بنزوکسازین به این روش با بهره خوب تا آلی ...
15 صفحه اولModeling Organic Chemistry and Planning Organic Synthesis
Organic Synthesis is a computationally challenging practical problem concerned with constructing a target molecule from a set of initially available molecules via chemical reactions. This paper demonstrates how organic synthesis can be formulated as a planning problem in Artificial Intelligence, and how it can be explored using the state-of-the-art domain independent planners. To this end, we d...
متن کاملSilicon hydrides in organic synthesis
In the past few years we have developed an array of composite reducing systems based on combinations of tin or silicon hydrides with various transition-metal homogeneous catalysts such as palladium(O), ruthenium(I1) and molybdenum(0) complexes. These represent a useful family of reducing media that effect highly selective reductions of various organic functional groups, such as allylic heterosu...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: ACS Catalysis
سال: 2023
ISSN: ['2155-5435']
DOI: https://doi.org/10.1021/acscatal.3c01174